Apple:

With Wi-Fi Assist, you can stay connected to the Internet even if you have a poor Wi-Fi connection. For example, if you’re using Safari with a poor Wi-Fi connection and a webpage doesn’t load, Wi-Fi Assist will activate and automatically switch to cellular so that the webpage continues to load. You can use Wi-Fi Assist with most apps like Safari, Apple Music, Mail, Maps, and more.

There’s interesting information about when iOS is and isn’t allowed to use the feature, as well.